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The vapor pressure of water at 45.0 °C is 71.93 mmHg.What is the vapor pressure of water over a solution prepared from 75.0 g of citric acid (C6H8O7) in 0.420 kg of water at this temperature?


A) 1.22 mmHg
B) 42.3 mmHg
C) 43.0 mmHg
D) 70.7 mmHg
E) 73.2 mmHg

F) C) and D)
G) B) and D)

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D

Using your knowledge of osmosis or osmotic pressure explain the following statement: Meat that is salted before cooking tends to dry out.

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The water passes thr...

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A solution that contains 55.0 g of ascorbic acid (VitaminC) in 250.g of water freezes at -2.34°C.Calculate the molar mass (in units of g/mol) of the solute.Kf of water is 1.86°C/m.


A) 1.26
B) 10.9
C) 43.6
D) 175
E) 277

F) C) and D)
G) None of the above

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The solubility of gases in water usually increases with


A) increasing pressure and increasing temperature
B) increasing temperature and decreasing pressure
C) decreasing temperature and increasing pressure
D) decreasing temperature and decreasing pressure
E) increasing temperature only

F) A) and B)
G) A) and C)

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What is the osmotic pressure of a solution prepared from 13.7 g of the electrolyte HCl and enough water to make 0.500 L of solution at 18°C?


A) 0.55 atm
B) 1.10 atm
C) 8.95 atm
D) 17.9 atm
E) 35.9 atm

F) B) and D)
G) A) and C)

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The vapor pressure of water at 20°C is 17.5 mmHg.What is the vapor pressure of water over a solution prepared from 2.00 × 102 g of sucrose (C12H22O11) and 3.50 × 102 g water?


A) 0.51 mmHg
B) 16.0 mmHg
C) 17.0 mmHg
D) 18.0 mmHg
E) 19.4 mmHg

F) C) and D)
G) B) and E)

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Calculate the mole fraction of KI in a solution made by dissolving 3.4 g of KI in 5.8 g of water.


A) 0.060
B) 0.064
C) 0.37
D) 0.59
E) 6.4

F) A) and C)
G) All of the above

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Some KCl is dissolved in water at 25°C, where it completely dissociates.The vapor pressure of pure water at 25°C is 28.3 mmHg.Estimate the mass in grams of KCl needed per liter of pure water to reduce the vapor pressure of water at 25°C by 5%.

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A 1.35 m solution of NaOCl in water is prepared.What is the mole fraction of the NaOCl?


A) 0.0135
B) 0.0243
C) 0.0271
D) 0.0237
E) 0.0263

F) D) and E)
G) A) and B)

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Determine the mass percent HCl in a 1.2 M solution of hydrochloric acid with a density of 1.019 g/mL?


A) 3.0 %
B) 4.3 %
C) 8.6 %
D) 13%
E) 30.%

F) A) and E)
G) B) and C)

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What is the molarity of a solution that is 7.00% by mass magnesium sulfate and has a density of 1.071 g/mL?


A) 0.0890 M
B) 0.496 M
C) 0.543 M
D) 0.623 M
E) 1.32 M

F) B) and E)
G) A) and D)

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D

What is the osmotic pressure of a 0.25 M solution of sucrose at 37°C? (R = 0.0821 L.atm/K.mol)


A) 6.6 × 10-5 atm
B) 0.76 atm
C) 6.4 atm
D) 100 atm
E) 940 atm

F) A) and B)
G) A) and C)

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C

The density of a 20.3 M CH3OH (methanol) solution is 0.858 g/mL.What is the molality of this solution? H2O is the solvent.


A) 17.4 m
B) 20.8 m
C) 23.7 m
D) 70.0 m
E) 97.6 m

F) C) and D)
G) A) and D)

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What is the mass percent CH3OH of a 0.256 m CH3OH(aq) solution.


A) 0.819 %
B) 0.992 %
C) 1.23 %
D) 1.29 %
E) 1.51 %

F) B) and E)
G) A) and C)

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What is the percent CsCl by mass in a 0.711 M CsCl solution that has a density of 1.091 g/mL?


A) 3.87 × 10-4 %
B) 3.87 × 10-1 %
C) 11.0 %
D) 1.10 %
E) 6.50 × 10-2 %

F) A) and B)
G) A) and C)

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Assuming 100% dissociation, which of the following compounds is listed incorrectly with its van't Hoff factor i?


A) Na2SO4, i = 3
B) NH4NO3, i = 2
C) Sucrose, i = 1
D) Al2(SO4) 3, i = 4
E) Mg(NO3) 2, i = 3

F) B) and C)
G) B) and D)

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Calculate the freezing point of a solution made from 22.0 g of octane (C8H18) dissolved in 148.0 g of benzene.Benzene freezes at 5.50°C and its Kf value is 5.12°C/m.


A) -1.16°C
B) 0.98°C
C) 5.49°C
D) 6.66°C
E) 12.2°C

F) A) and B)
G) All of the above

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To interconvert the concentration units of molality (m)and mass percent, you must also know the density of the solution.

A) True
B) False

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The vapor pressure of a solution depends on the chemical nature of the non-volatile solute

A) True
B) False

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What is the boiling point of an aqueous solution of a nonelectrolyte that has an osmotic pressure of 10.50 atm at 25°C? Kb of water is 0.52°C/m.Assume the density of the solution is the same as that of pure water.


A) 0.22°C
B) 0.429°C
C) 99.78°C
D) 100.22°C
E) 100.43°C

F) C) and D)
G) A) and B)

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